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Elsevier

Libros en Química

  • Palladium in Heterocyclic Chemistry

    A Guide for the Synthetic Chemist
    • 1 Edición
    • Volumen 20
    • Gordon Gribble + 1 más
    • Inglés

  • Palladium in Heterocyclic Chemistry

    A Guide for the Synthetic Chemist
    • 1 Edición
    • Volumen 20
    • Gordon Gribble + 1 más
    • Inglés

  • Bioactive Natural Products (Part D)

    V23
    • 1 Edición
    • Atta-ur Rahman
    • Inglés
    Natural products play an integral and ongoing role in promoting numerous aspects of scientific advancement, and many aspects of basic research programs are intimately related to natural products. The significance, therefore, of the Studies in Natural Product Chemistry series, edited by Professor Atta-ur-Rahman, cannot be overestimated. This volume, in accordance with previous volumes, presents us with cutting-edge contributions of great importance.

  • Bioactive Natural Products (Part C)

    V22
    • 1 Edición
    • Atta-ur Rahman
    • Inglés
    Natural products play an integral and ongoing role in promoting numerous aspects of scientific advancement, and many aspects of basic research programs are intimately related to natural products. The significance, therefore, of the Studies in Natural Product Chemistry series, edited by Professor Atta-ur-Rahman, cannot be overestimated. This volume, in accordance with previous volumes, presents us with cutting-edge contributions of great importance.

  • Amphiphilic Block Copolymers

    Self-Assembly and Applications
    • 1 Edición
    • P. Alexandridis + 1 más
    • Inglés
    It is the belief of the editors of this book that the recognition of block copolymers as being amphiphilic molecules and sharing common features with other well-studied amphiphiles will prove beneficial to both the surfactant and the polymer communities. An aim of this book is to bridge the two communities and cross-fertilise the different fields. To this end, leading researchers in the field of amphiphilic block copolymer self-assembly, some having a background in surfactant chemistry, and others with polymer physics roots, have agreed to join forces and contribute to this book.The book consists of four entities. The first part discusses theoretical considerations behind the block copolymer self-assembly in solution and in the melt. The second part provides case studies of self-assembly in different classes of block copolymers (e.g., polyethers, polyelectrolytes) and in different environments (e.g., in water, in non-aqueous solvents, or in the absence of solvents). The third part presents experimental tools, ranging from static (e.g., small angle neutron scattering) to dynamic (e.g., rheology), which can prove valuable in the characterization of block copolymer self-assemblies. The fourth part offers a sampling of current applications of block copolymers in, e.g., formulations, pharmaceutics, and separations, applications which are based on the unique self-assembly properties of block copolymers.

  • Micro Mechanical Transducers

    Pressure Sensors, Accelerometers and Gyroscopes
    • 1 Edición
    • Volumen 8
    • Min-hang Bao
    • S. Middelhoek
    • Inglés
    Some years ago, silicon-based mechanical sensors, like pressure sensors, accelerometers and gyroscopes, started their successful advance. Every year, hundreds of millions of these devices are sold, mainly for medical and automotive applications. The airbag sensor on which research already started several decades ago at Stanford University can be found in every new car and has saved already numerous lives. Pressure sensors are also used in modern electronic blood pressure equipment. Many other mechanical sensors, mostly invisible to the public, perform useful functions in countless industrial and consumer products. The underlying physics and technology of silicon-based mechanical sensors is rather complex and is treated in numerous publications scattered throughout the literature. Therefore, a clear need existed for a handbook that thoroughly and systematically reviews the present basic knowledge on these devices.After a short introduction, Professor Bao discusses the main issues relevant to silicon-based mechanical sensors. First a thorough treatment of stress and strain in diaphragms and beams is presented. Next, vibration of mechanical structures is illuminated, followed by a chapter on air damping. These basic chapters are then succeeded by chapters in which capacitive and piezoresistive sensing techniques are amply discussed. The book concludes with chapters on commercially available pressure sensors, accelerometers and resonant sensors in which the above principles are applied. Everybody, involved in designing silicon-based mechanical sensors, will find a wealth of useful information in the book, assisting the designer in obtaining highly optimized devices.

  • Physical Chemistry of Polymer Solutions

    Theoretical Background
    • 1 Edición
    • K. Kamide + 1 más
    • Inglés
    This book is mainly concerned with building a narrow but secure ladder which polymer chemists or engineers can climb from the primary level to an advanced level without great difficulty (but by no means easily, either).This book describes some fundamentally important topics, carefully chosen, covering subjects from thermodynamics to molecular weight and its distribution effects. For help in self-education the book adopts a "Questions and Answers" format. The mathematical derivation of each equation is shown in detail. For further reading, some original references are also given. Numerous physical properties of polymer solutions are known to be significantly different from those of low molecular weight solutions. The most probable explanation of this obvious discrepancy is the large molar volume ratio of solute to solvent together with the large number of consecutive segments that constitute each single molecule of the polymer chains present as solute. Thorough understanding of the physical chemistry of polymer solutions requires some prior mathematical background in its students. In the original literature, detailed mathematical derivations of the equations are universally omitted for the sake of space-saving and simplicity. In textbooks of polymer science only extremely rough schemes of the theories and then the final equations are shown. As a consequence, the student cannot learn, unaided, the details of the theory in which he or she is interested from the existing textbooks; however, without a full understanding of the theory, one cannot analyze actual experimental data to obtain more basic and realistic physical quantities. In particular, if one intends to apply the theories in industry, accurate understanding and ability to modify the theory are essential.

  • The Handbook of Organic Compounds, Three-Volume Set

    NIR, IR, R, and UV-Vis Spectra Featuring Polymers and Surfactants
    • 1 Edición
    • Jerry Workman Jr.
    • Inglés
    The Handbook of Organic Compounds: NIR, IR, Raman, and UV-Vis Spectra Featuring Polymers and Surfactants represents a compendium of practical spectroscopic methodology, comprehensive reviews, and basic information for organic materials, surfactants, and polymer spectra covering the Ultraviolet, Visible, Near Infrared, Infrared, Raman and Dielectric measurement techniques. This set represents a complementary organic compound handbook to the Nyquist inorganic handbook, published in 1996. This set comprises the first comprehensive multi-volume handbook to provide basic coverage for UV-Vis, 4th overtone NIR, 3rd overtone NIR, NIR, Infrared, Raman spectra, and Dielectric data for common organic compounds, polymers, surfactants, contaminants, and inorganic materials commonly encountered in the laboratory. The text includes a description and reviews of interpretive and chemometric techniques used for spectral data analysis. The spectra included within the atlas are useful for identification purposes as well as pedagogical for the instruction of the various interpretive and data processing methods discussed. This work is designed to be of help to students and vibrational spectroscopists in their efforts of daily spectral interpretation and data processing of organic spectra, polymers, and surfactants. All spectra are presented in wavenumber and transmittance, with the addition of ultraviolet, visible, 4th overtone NIR, 3rd overtone NIR, and NIR spectra also represented in nanometers and absorbance space. In addition, some Horizontal infrared ATR spectra are presented in wavenumber and absorbance space. All spectra are shown with essential peaks labeled in their respective units. The material in this handbook was contributed to by several individuals, and comments were received from a variety of prominent workers in the field of molecular spectroscopy. This type of handbookproject is a daunting task. This Handbook can provide a valuable reference for the daily activities of students and professionals working in modern molecular spectroscopy laboratories.

  • Heme-Fe Proteins

    • 1 Edición
    • Volumen 51
    • Inglés
    Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bioinorganic to solid state. This acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.

  • Handbook of Heterocyclic Chemistry

    • 2 Edición
    • Alan R. Katritzky + 4 más
    • Inglés
    Heterocyclic chemistry is the largest of the classical divisions of organic chemistry. Heterocyclic compounds are widely distributed in Nature, playing a vital role in the metabolism of living cells. Their practical applications range from extensive clinical use to fields as diverse as agriculture, photography, biocide formulation and polymer science. The range of known compounds is enormous, encompassing the whole spectrum of physical, chemical and biological properties. This book provides a balanced, concise and informative account of heterocyclic chemistry that will be suitable for graduate or advanced undergraduate students and a convenient reference book for research workers, for both specialists int he field and those whose expertise lies in other areas but who nevertheless need information on heterocylic chemistry. The Handbook of Heterocyclic Chemistry is illustrated throughout with thousands of clearly drawn chemical structures. The highly systematic coverage given to the subject makes this the most authoritative one-volume account of modern heterocyclic chemistry available.

  • Radioactivity in the Environment

    Physicochemical aspects and applications
    • 1 Edición
    • Vlado Valkovic
    • Inglés
    Numerous sources of ionizing radiation can lead to human exposure: natural sources, nuclear explosions, nuclear power generation, use of radiation in medical, industrial and research purposes, and radiation emitting consumer products. Before assessing the radiation dose to a population one requires a precise knowledge of the activity of a number of radionuclides. The basis for the assessment of the dose to a population from a release of radioactivity to the environment, the estimation of the potential clinical heath effects due to the dose received and, ultimately, the implementation of countermeasures to protect the population, is the measurement of radioactive contamination in the environment after the release.It is the purpose of this book to present the facts about the presence of radionuclides in the environment, natural and man made. There is no aspect of radioactivity, which has marked the passing century, not mentioned or discussed in this book.

  • Non-Linear Mass Transfer and Hydrodynamic Stability

    • 1 Edición
    • C.B. Boyadjiev + 1 más
    • Inglés
    Surveyed in this book are the kinetics of non-linear mass transfer and its effects on hydrodynamic stability in systems with intensive interphase mass transfer, in electrochemical systems with high current density and in chemically reacting systems.In Part 1 the non-linear mass transfer as a result of an intensive interphase mass transfer in the gas (liquid)-solid surface, gas-liquid and liquid-liquid systems is considered in the duffusion boundary layer approximation as well as in flat channel taking the longitudinal diffusion into account. The influence of the direction of the intensive interphase mass transfer on heat transfer and multi-component mass transfer is illustrated.Part 2 discusses non-linear mass transfer in electrochemical systems with high current density using the examples of the anode dissolving of metals in the electrolyte flow and the electro-separation of metals out of concentrated solutions. The theory of the measured electrochemical treatment of metals and alloys, which is a method of wide practical use, has been elaborated on this basis.In Part 3 the non-linear mass transfer in chemically reacting systems is considered in the cases of: non-linearity of the equations of the chemical reaction's kinetics and intensive interphase mass transfer or thermo-capillary effect due to chemical reactions. On this basis, the mechanisms and the macro-kinetics of the chemical transformations in the gas-liquid systems are discussed.Part 4 is dedicated to the chemical reaction kinetics in stationary two phase systems at an arbitrary contact time between phases.In Part 5 the effects of concentration gradients are considered in the approximations of the linear theory of the hydrodynamic stability of almost parallel flows.In systems with intensive interphase mass transfer, the Marangoni effect could also be observed, beside the effect of non-linear mass transfer. A comparative analysis of both effects is made in this book.

  • Population Balances

    Theory and Applications to Particulate Systems in Engineering
    • 1 Edición
    • Doraiswami Ramkrishna
    • Inglés
    Engineers encounter particles in a variety of systems. The particles are either naturally present or engineered into these systems. In either case these particles often significantly affect the behavior of such systems. This book provides a framework for analyzing these dispersed phase systems and describes how to synthesize the behavior of the population particles and their environment from the behavior of single particles in their local environments. Population balances are of key relevance to a very diverse group of scientists, including astrophysicists, high-energy physicists, geophysicists, colloid chemists, biophysicists, materials scientists, chemical engineers, and meteorologists. Chemical engineers have put population balances to most use, with applications in the areas of crystallization; gas-liquid, liquid-liquid, and solid-liquid dispersions; liquid membrane systems; fluidized bed reactors; aerosol reactors; and microbial cultures. Ramkrishna provides a clear and general treatment of population balances with emphasis on their wide range of applicability. New insight into population balance models incorporating random particle growth, dynamic morphological structure, and complex multivariate formulations with a clear exposition of their mathematical derivation is presented. Population Balances provides the only available treatment of the solution of inverse problems essential for identification of population balance models for breakage and aggregation processes, particle nucleation, growth processes, and more. This book is especially useful for process engineers interested in the simulation and control of particulate systems. Additionally, comprehensive treatment of the stochastic formulation of small systems provides for the modeling of stochastic systems with promising new areas of applications such as the design of sterilization systems and radiation treatment of cancerous tumors.

  • Advances in Heterocyclic Chemistry

    • 1 Edición
    • Volumen 77
    • Inglés
    Established in 1960, Advances in Heterocyclic Chemistry is the definitive serial in the area--one of great importance to organic chemists, polymer chemists, and many biological scientists. Written by established authorities in the field, the comprehensive reviews combine descriptive chemistry and mechanistic insight and yield an understanding of how the chemistry drives the properties.

  • Advances in Heterocyclic Chemistry

    • 1 Edición
    • Volumen 76
    • Inglés
    Established in 1960, Advances in Heterocyclic Chemistry is the definitive serial in the area--one of great importance to organic chemists, polymer chemists, and many biological scientists. Written by established authorities in the field, the comprehensive reviews combine descriptive chemistry and mechanistic insight and yield an understanding of how the chemistry drives the properties.

  • Chemical Thermodynamics: Advanced Applications

    Advanced Applications
    • 1 Edición
    • J. Bevan Ott + 1 más
    • Inglés
    This book is an excellent companion to Chemical Thermodynamics: Principles and Applications. Together they make a complete reference set for the practicing scientist. This volume extends the range of topics and applications to ones that are not usually covered in a beginning thermodynamics text. In a sense, the book covers a "middle ground" between the basic principles developed in a beginning thermodynamics textbook, and the very specialized applications that are a part of an ongoing research project. As such, it could prove invaluable to the practicing scientist who needs to apply thermodynamic relationships to aid in the understanding of the chemical process under consideration. The writing style in this volume remains informal, but more technical than in Principles and Applications. It starts with Chapter 11, whichsummarizes the thermodynamic relationships developed in this earlier volume. For those who want or need more detail, references are given tothe sections in Principles and Applications where one could go to learn more about the development, limitations, and conditions where these equations apply. This is the only place where Advanced Applications ties back to the previous volume. Chapter 11 can serve as a review of the fundamental thermodynamic equations that are necessary for the more sophisticated applications described in the remainder of this book. This may be all that is necessary for the practicing scientist who has been away from the field for some time and needs some review. The remainder of this book applies thermodynamics to the description of a variety of problems. The topics covered are those that are probably of the most fundamental and broadest interest. Throughout the book, examples of "real" systems are used as much as possible. This is in contrast to many books where "generic" examples are used almost exclusively. A complete set of references to all sources of data and to supplementary reading sources is included. Problems are given at the end of each chapter. This makes the book ideally suited for use as a textbook in an advanced topics course in chemical thermodynamics.

  • Handbook on the Physics and Chemistry of Rare Earths

    • 1 Edición
    • Volumen 28
    • Inglés
    Even at the beginning of the new millenium the rare earths still remain, to a certain extent, a mystery. The chapters in this volume will help to unravel some of these. In the filling of the 4f electronic orbitals the lanthanides defy the elementary aufbau principle that underlies the periodic sequence of the elements, and the authors of the first chapter introduce the readers to the basic physics of the orbital collapse leading to that failure. Furthermore an explanation is offered in terms of double-well potentials. The phenomenon is illustrated using the valence transitions observed in some of the rare earth atoms, including Sm group metals and the higher oxides of cerium, praseodymium and terbium. In the second chapter the synthesis and structure of the many types of rare earth halides are described. They have been described as simple, complex, binary, ternary and multinuclear complex, and other categories needed to deal with the most studied of the rare earth compounds. The structure types are skillfully illustrated to show the elementary architecture of each type.In chapter three the authors discuss the science and applications of rare earth super ionic conductors as solid electrolytes. Conduction by oxygen and fluorine anions as well as hydrogen and other cations associated with these electrolytes is emphasized. They deal with extrinsic and intrinsic types together with their associated structures and structural types including structural defects. The chapter concludes with an outline of the many applications of solid electrolytes.Chapter four introduces the reader to the principles that underlie thermoluminescence and its application to dosimetry and provides detailed information on the R-activated phosphors that support dosimetry. This is a selective review of detailed literature based on the areas making most progress.The final chapter elaborates on the data gained by the studies and interpretation around the analytical separation of the individual rare earth elements utilizing chromatographic techniques. The authors describe the fundamental chemistry that underpins contemporary analytical separation techniques for lanthanide separation and analysis. This is done after a description of the rich assortment of separation methods in use has been introduced.

  • Fluid Catalytic Cracking Handbook

    An Expert Guide to the Practical Operation, Design, and Optimization of FCC Units
    • 2 Edición
    • Reza Sadeghbeigi
    • Inglés
    This thoroughly updated edition of Fluid Catalytic Cracking Handbook provides practical information on the design, operation, troubleshooting, and optimization of fluid catalytic cracking (FCC) facilities. Based on the author's years of field experience, this expanded, second edition covers the latest technologies to improve the profitability and reliability of the FCC units, and provides several "no-to-low-cost" practical recommendations. A new chapter supplies valuable recommendations for debottlenecking and optimizing the performance of cat cracker operations.

  • Advanced Inorganic Fluorides: Synthesis, Characterization and Applications

    • 1 Edición
    • T. Nakajima + 2 más
    • Inglés
    This book summarizes recent progresses in inorganic fluorine chemistry. Highlights include new aspects of inorganic fluorine chemistry, such as new synthetic methods, structures of new fluorides and oxide fluorides, their physical and chemical properties, fluoride catalysts, surface modifications of inorganic materials by fluorination process, new energy conversion materials and industrial applications. Fluorine has quite unique properties (highest electronegativity; very small polarizability). In fact, fluorine is so reactive that it forms fluorides with all elements except with the lightest noble gases helium, neon and argon. Originally, due to its high reactivity, fluoride chemistry faced many technical difficulties and remained undeveloped for many years. Now, however, a large number of fluorine-containing materials are currently produced for practical uses on an industrial scale and their applications are rapidly extending to many fields. Syntheses and structure analyses of thermodynamically unstable high-oxidation-state fluorides have greatly contributed to inorganic chemistry in this decade. Fluoride catalysts and surface modifications using fluorine are developing a new field of fluorine chemistry and will enable new syntheses of various compounds. The research on inorganic fluorides is now contributing to many chemical energy conversion processes such as lithium batteries. Furthermore, new theoretical approaches to determining the electronic structures of fluorine compounds are also progressing. On the industrial front, the use of inorganic fluorine compounds is constantly increasing, for example, in semi-conductor industry. "Advanced Inorganic Fluorides: Synthesis, Characterization and Applications" focuses on these new features in inorganic fluorine chemistry and its industrial applications. The authors are outstanding experts in their fields, and the contents of the book should prove to be of valuable assistance to all chemists, graduates, students and researchers in the field of fluorine chemistry.

  • Wavelets in Chemistry

    • 1 Edición
    • Volumen 22
    • Beata Walczak
    • Inglés
    Wavelets seem to be the most efficient tool in signal denoising and compression. They can be used in an unlimited number of applications in all fields of chemistry where the instrumental signals are the source of information about the studied chemical systems or phenomena, and in all cases where these signals have to be archived. The quality of the instrumental signals determines the quality of answer to the basic analytical questions: how many components are in the studied systems, what are these components like and what are their concentrations? Efficient compression of the signal sets can drastically speed up further processing such as data visualization, modelling (calibration and pattern recognition) and library search. Exploration of the possible applications of wavelets in analytical chemistry has just started and this book will significantly speed up the process.The first part, concentrating on theoretical aspects, is written in a tutorial-like manner, with simple numerical examples. For the reader's convenience, all basic terms are explained in detail and all unique properties of wavelets are pinpointed and compared with the other types of basis function. The second part presents applications of wavelets from many branches of chemistry which will stimulate chemists to further exploration of this exciting subject.

  • Main Chemistry Group

    • 1 Edición
    • Volumen 50
    • Inglés
    Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bioinorganic to solid state. This acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.

  • Analysis of Neuropeptides by Liquid Chromatography and Mass Spectrometry

    • 1 Edición
    • Volumen 6
    • D.M. Desiderio
    • Inglés

  • Isoelectric Focusing: Theory, Methodology and Application

    • 1 Edición
    • Volumen 11
    • Pier Giorgio Righetti
    • Inglés
    This book deals with theoretical and practical developments of IEF and offers detailed methodology for many of the commonly used procedures, such as IEF in gels. It is intended both as a reference guide and a practical manual.

  • Handbook of Non-Invasive Drug Delivery Systems

    Science and Technology
    • 1 Edición
    • Vitthal S. Kulkarni
    • Inglés
    With the improvements in formulation science and certain transdermal delivery technologies, the non-invasive mode of drug delivery is now ready to compete with traditional methods of oral and injectible routes of drug delivery. The Handbook of Non-Invasive Drug Delivery Systems encompasses the broad field of non-invasive drug delivery systems that include drug delivery via topical, transdermal-passive, transdermal-active (device- aided enhanced penetration), trans-mucosal membrane, trans-ocular membrane as well as delivery via alveolar membrane from inhaled medication. Patient compliance has been found to be much higher when administrated by non-invasive routes and therefore they are considered to be a preferred mode of drug delivery. The book includes both science and technological aspects of new drug delivery systems. Its unique focus is that it is on new drug delivery systems that are considered to be "non-invasive". Other unique features include a chapter on Regulatory Aspects of non-invasive systems and one on FDA guidance for topical nano-drug delivery. Two chapters covering market trends and perspectives, as well as providing guidance to those marketing such systems are also included.

  • Pyrolysis Mass Spectrometry of Recent and Fossil Biomaterials

    • 1 Edición
    • Volumen 3
    • H.L.C. Meuzelaar + 2 más
    • Inglés

  • Micromachining Using Electrochemical Discharge Phenomenon

    Fundamentals and Application of Spark Assisted Chemical Engraving
    • 1 Edición
    • Rolf Wuthrich + 1 más
    • Inglés
    This book explains the fundamentals of SACE, promotes the technology, and encourages researchers and engineers from industry to use it for their specific applications. Therefore, the book, after presenting in details the fundaments of SACE (in particular the Electrochemical Discharges), deals mainly with practical aspects of implementing the machining technology. The book is written so that researchers from fields other than micro-technology (e.g., from life science) will be able to build a simple machining set-up, together with his mechanical work-shop, for individual needs.

  • Practical Process Research and Development

    • 1 Edición
    • Neal G. Anderson
    • Inglés
    This book provides a comprehensive, step-by-step approach to organic process research and development in the pharmaceutical, fine chemical, and agricultural chemical industries. Process R&D describes the steps taken, following synthesis and evaluation, to bring key compounds to market in a cost-effective manner. More people are being hired for work in this area as increasing numbers of drug candidates are identified through combinatorial chemistry and high-throughput screening. The book is directed to industrial (primarily organic) chemists, and academicians (particularly those involved in a growing number of start-up companies) and students who need insight into industrial process R&D. Current books do not describe hands-on, step-by-step, approaches to solving process development problems, including route, reagent, and solvent selection; optimising catalytic reactions; chiral syntheses; and "green chemistry." "Practical Process Research and Development" will be a valuable resource for researchers, managers, and graduate students.

  • Job$ in the Drug Indu$try

    A Career Guide for Chemists
    • 1 Edición
    • Richard J. Friary
    • Inglés
    This book is intended to help newly graduated chemists, particularly organic chemists, at all levels from bachelors to post-doctorates, find careers in the North American pharmaceutical industry. It will serve as a practical, detailed guiedbook for job seekers as well a reference work for faculty advisers, research supervisors, development officers, employment agents, and personnel managers in the industry. The book gathers in a single volume the fundamentals of getting an industrial job as a medicinal or process chemist, and covers all aspects of a chemist's job--scientific, financial, and managerial--within a pharmaceutical/biote... company. Other scientists looking for jobs as analytical or physical chemists and even biochemists and biologists will find the book useful. The valuable appendix is a unique compendium of 365 commercial, governmental, or non-profit institutions that comprise the North American pharmaceutical industry.

  • Bioactive Natural Products (Part B)

    V21
    • 1 Edición
    • Atta-ur Rahman
    • Inglés
    Natural products play an integral and ongoing role in promoting numerous aspects of scientific advancement, and many aspects of basic research programs are intimately related to natural products. The significance, therefore, of the Studies in Natural Product Chemistry series, edited by Professor Atta-ur-Rahman, cannot be overestimated. This volume, in accordance with previous volumes, presents us with cutting-edge contributions of great importance.

  • Advances in Supramolecular Chemistry

    • 1 Edición
    • Volumen 6
    • G.W. Gokel
    • Inglés
    In this volume, inorganic, organic, and bioorganic chemistry are represented in contributions from around the world. Pioneering work in self-assembled structures organized by the use of transition metals is described in chapter 1, followed by details of extensive studies of self-assembled structures formed from various biomolecules in chapter 2. The next two chapters describe the formation of spherical molecular containers and their understanding of such structures based on Platonic and Archimedean solids, and the fascinating family of synthetic peptide receptors and the interactions that can be explored using these host molecules. In chapter 5 a mixture of computational chemistry, drug design, and synthetic organic and inorganic chemistry in the development of superoxide dismutase mimics is described. The final two chapters discuss the bioorganic and supramolecular principles required for the design of synthetic artificial enzymes, and the supramolecular self-assembly and its possible role in the origin of life.It is hoped that this broad, international view of supramolecular chemistry and the many directions it leads will be of interest to those already in the field. It is also hoped that those outside the field may see extensions of their own work that will bring them into it.

  • Advances in Sulfur Chemistry

    • 1 Edición
    • Volumen 2
    • C.M. Rayner
    • Inglés
    This volume is a testament to the continuing importance of sulfur chemistry, and the tremendous progress that has been made in recent years.

  • Nucleation

    • 1 Edición
    • Dimo Kashchiev
    • Inglés
    This book represents a detailed and systematic account of the basic principles, developments and applications of the theory of nucleation.The formation of new phases begins with the process of nucleation and is, therefore, a widely spread phenomenon in both nature and technology. Condensation and evaporation, crystal growth, electrodeposition, melt crystallization, growth of thin films for microelectronics, volcano eruption and formation of particulate matter in space are only a few of the processes in which nucleation plays a prominent role.The book has four parts, which are devoted to the thermodynamics of nucleation, the kinetics of nucleation, the effect of various factors on nucleation and the application of the theory to other processes, which involve nucleation. The first two parts describe in detail the two basic approaches in nucleation theory - the thermodynamic and the kinetic ones. They contain derivations of the basic and most important formulae of the theory and discuss their limitations and possibilities for improvement. The third part deals with some of the factors that can affect nucleation and is a natural continuation of the first two chapters. The last part is devoted to the application of the theory to processes of practical importance such as melt crystallization and polymorphic transformation, crystal growth and growth of thin solid films, size distribution of droplets and crystallites in condensation and crystallization. The book is not just an account of the status quo in nucleation theory - throughout the book there are a number of new results as well as extensions and generalisations of existing ones.

  • Alkaloids: Chemical and Biological Perspectives

    • 1 Edición
    • Volumen 14
    • S.W. Pelletier
    • Inglés
    Volume 14 of this series presents three interesting reviews of research on alkaloids. Chapter 1, by Paul L. Schiff, Jr., is a monumental effort, presenting a selective, comprehensive tabular review of research on the bisbenzylisoquinolin... alkaloids, with an analysis of the respective alkaloid types. The chapter should serve as a very useful tool for the bench research scientist who is involved in the isolation and elucidation of structures of bisbenzylisoquinolin... alkaloids. Moreover, the data in these tables provides the botanical distribution and occurrence (family, genus, species) of the various classes of these alkaloids. The alkaloids are also categorized by their molecular weights and structural types. Chapter 2, by Toh-Seok Kam, is a review of alkaloids derived from Malaysian flora. Malaysia's position near the Equator confers on it a tropical climate characterized by high temperatures, humidity, and rainfall, conditions favorable for plant life that has resulted in a rich flora of about 15,000 species of higher plants. This review concentrates on work published during the past twenty years and where appropriate compares the occurrence of alkaloids with studies of similar plants from countries neighboring to Malaysia, especially Thailand and Indonesia. Chapter 3, by Jie Jack Li, presents a collection of very interesting total syntheses of naturally occurring indole alkaloids where palladium chemistry plays a central role in the syntheses. Five different types of palladium-mediated reactions are treated: (1) oxidative cyclization reactions promoted by palladium (II) species; (2) transmetallation reactions with organoboranes, organostannanes, and organozinc reagents; (3) inter- and intramolecular Heck reactions; (4) reactions with &pgr;-allylpalla... as the intermediate; and (5) reactions using C-N bond formation as the key step for the synthesis.

  • Fundamentals of Equilibrium and Steady-State Thermodynamics

    • 1 Edición
    • N.W. Tschoegl
    • Inglés
    This book summarizes the salient features of both equilibrium and steady-state thermodynamic theory under a uniform postulatory viewpoint. The emphasis is upon the formal aspects and logical structure of thermodynamic theory, allowing it to emerge as a coherent whole, unfettered by much of those details which - albeit indispensable in practical applications - tend to obscure this coherent structure. Largely because of this, statistical mechanics and reference to molecular structure are, barring an occasional allusion, avoided. The treatment is, therefore, 'classical', or - using a perhaps more appropriate word - 'phenomenological'. The volume almost exclusively deals with 'ideal' systems, given that the treatment of 'real' systems properly belongs in the realm of applied, rather than theoretical thermodynamics. For these reasons, only selected ideal systems are covered. Ideal gases are discussed extensively. The ideal solution is treated as an example of a liquid system. The amorphous ideal rubber serves as an example of a solid. The formalism developed in these sections is a model for the treatment of other, more complex systems. This short structural overview is written in the hope that a knowledge of steady-state theory will deepen readers' understanding of thermodynamics as a whole.

  • The Chemistry and Technology of Furfural and its Many By-Products

    • 1 Edición
    • Volumen 13
    • K.J. Zeitsch
    • Inglés
    This book is a "world first", since the furfural industry has been traditionally secretive to the point of appearing shrouded in clouds of mystery. Even renowned encyclopedic works have published but scant and often erroneous information on the subject. Striking a healthy balance between theory and practice, the book leads the reader from reaction mechanisms and kinetics to the technology of making furfural by various old and new processes, using conventional raw materials or sulfite waste liquor. Detailed discussions of means of increasing the yield are of great chemical and technological interest as well as of immense economic importance.From furfural proper, the treatise shifts to the fascinating field of wanted and unwanted by-products ranging from largely unutilized carboxylic acids to troublesome impurities such as 5-methyl furfural and 2-furyl methyl ketone, and then to extremely valuable serendipitous flavor compounds such as diacetyl and 2,3-pentanedione. A wide variety of derivatives are discussed; considerable space is devoted to polytetrahydrofuran, an important building block of stretchable synthetic fibers, while furan resins from both furfural and furfuryl alcohol are given the attention commensurate with their industrial importance. Notable supplementary chapters cover the in-line measurement of furfural, the treatment of furfural waste water, and various aspects of corrosion. A chapter on the applications of furfural elaborates not only traditional uses in extracting petroleum and vegetable oils but also the sensational discovery that furfural is a highly effective "indirect nematocide". Without becoming toxic, it changes the microflora of the soil by stimulating bacteria antagonistic to nematodes, thereby reducing the nematode population to zero, at an unprecedented low price. It is believed that this application will be the principal outlet for furfural in the future.A comprehensive list of physical properties, some never published before, make the book an indispensable companion for producers, users and researchers alike.

  • Advances in Free Radical Chemistry

    • 1 Edición
    • Volumen 2
    • S.Z. Zard
    • Inglés
    This series is designed to provide a vehicle in which investigators, who have demonstrated a high degree of competence in some aspect of free radical chemistry, can present a particular area of interest. The series encompasses a wide variety of topics which are of current interest.

  • Dynamic Surface Tensiometry in Medicine

    • 1 Edición
    • Volumen 8
    • V.N. Kazakov + 4 más
    • Inglés
    Human biological liquids contain numerous low- and high-molecular weight surfactants. The human organism contains interfaces with enormous surfaces. The physicochemical and biochemical processes taking place at these interfaces are extremely important for the vital functions of the organism as a whole, and the interfacial properties may reflect peculiarities of age and sex, health and disease. The present book is the first attempt to systematically present the results of dynamic and equilibrium surface tensions measurements of serum and urine samples that were obtained from healthy humans of various sex and age, and to compare these results with measurements of biological liquids obtained from patients suffering from various diseases or with measurements of amniotic fluid obtained from women at various stages of pregnancy.Pulmonary medicine, especially neonatology, has systematically used interfacial tensiometry for studying pulmonary surfactant. In this particular area, significant progress was achieved in the treatment of diseases related to alterations of the lung surfactant system. We believe that, similar to the progress in pulmonary medicine attributed to surface chemical studies of lung surfactant, progress in other medical branches could be expected through studies of interfacial characteristics of other human biological liquids.For several years the authors of this book have been engaged in studies aimed at the improvement of the maximum bubble pressure method, resulting in the development of computer controlled tensiometers which are capable of measuring dynamic surface tensions within a wide range of surface lifetime. In addition to the measurement techniques, a correct interpretation and analysis of the tensiometric data obtained is extremely important. The kinetic theory of adsorption from solutions, and the theory of equilibrium adsorption layers of surfactant/protein mixtures provide the basis for both the choice of the most characteristic parameters of tensiograms and the analysis of the results. Some theoretical models describing the adsorption of proteins are presented in Chapter 1. The main theoretical and experimental issues related to the maximum bubble pressure technique as applied to biological liquids are presented in Chapter 2. A more detailed discussion of the differences of the various methods in use for measuring dynamic surface tension of biological fluids is provided in Chapter 3. Chapter 4 gives data from patients with kidney disease, Chapter 5 from patients with rheumatic diseases, Chapter 6 with pulmonary diseases, Chapter 7 with diseases of the central nervous system, and Chapter 8 with neoplasms.Dynamic interface tensiometry of human biological liquids is a fascinating new method which deserves a broad use for prospective studies of various diseases.

  • Advances in Atomic Spectroscopy

    • 1 Edición
    • Volumen 5
    • J. Sneddon
    • Inglés
    This fifth volume of the successful series Advances in Atomic Spectroscopy continues to discuss and investigate the area of atomic spectroscopy.It begins with a description of the use of various atomic spectroscopic methods and applications of speciation studies in atomic spectroscopy. The emphasis is on combining atomic spectroscopy with gas and liquid chromatography. In chapter two the authors describe new developments in tunable lasers and the impact they will have on atomic spectroscopy. The traditional methods of detection, such as photography and the photomultiplier, and how they are being replaced by new detectors is discussed in chapter three. The very active area of glow discharge atomic spectrometry is presented in chapter four where, after a brief introduction and historical review, the use of glow discharge lamps for atomic spectroscopy and mass spectrometry are discussed. Included in this discussion is geometry and radiofrequency power. The future of this source in atomic spectroscopy is also discussed. This comprehensive book is then completed with a look at the use of a laser-induced or laser-ablated plasma as a spectrochemical source for atomic emission spectrometry.

  • Advances in Carbohydrate Chemistry and Biochemistry

    • 1 Edición
    • Volumen 55
    • Inglés
    Since its inception in 1945, this serial has provided critical and integrating articles written by research specialists that integrate industrial, analytical, and technological aspects of biochemistry, organic chemistry, and instrumentation methodology in the study of carbohydrates. The articles provide a definitive interpretation of the current status and future trends in carbohydrate chemistry and biochemistry.

  • Advances in Cycloaddition

    • 1 Edición
    • Volumen 6
    • Michael Harmata
    • Inglés
    This volume presents work from six different groups working on various aspects of cycloaddition chemistry. José Mascareñas gives us a very interesting account of the chemistry of &Bgr;-alkoxy-&am... and related species. Al Padwa and Chris Staub discuss further advances in rhodium carbenoid chemistry and the unusual cycloaddition processes possible with these intermediates. Higher order cycloadditions mediated by transition metals highlight Jim Rigby's update on his group's efforts in this area. Lily Lee and John Snyder present us with a detailed account of the indole ring as a dienophile, challenging us to consider the untapped potential in this area. Brian Keay and Ian Hunt discuss the intramolecular Diels-Alder reactions of furan; a report that is both top-notch science, and what could be a great learning tool for students who need to see how fundamental chemical principles can and should be applied to synthetic problems. Finally, Kay Brummond introduces us to a new version of the Pauson-Khand reactions, one that will no doubt be further exploited in productive ways by her group well into the future.

  • The Physical Basis of Chemistry

    • 2 Edición
    • Warren S. Warren
    • Inglés
    If the text you're using for general chemistry seems to lack sufficient mathematics and physics in its presentation of classical mechanics, molecular structure, and statistics, this complementary science series title may be just what you're looking for. Written for the advanced lower-division undergraduate chemistry course, The Physical Basis of Chemistry, Second Edition, offers students an opportunity to understand and enrich the understanding of physical chemistry with some quantum mechanics, the Boltzmann distribution, and spectroscopy. Posed and answered are questions concerning everyday phenomena. Unlike other texts on this subject, however, Dr. Warren deals directly with the substance of the questions, avoiding the use of predigested material more appropriate for memorization exercises than for actual concrete learning. The only prerequisite is first-semester calculus or familiarity with one-variable derivatives. In this new edition, the entire text has been rewritten and keyed with an accompanying website, which contains instructive QuickTime movies on topics presented in the text to enhance student learning and participation.

  • Bioactive Natural Products (Part E)

    V24
    • 1 Edición
    • Atta-ur Rahman
    • Inglés
    Natural products play an integral and ongoing role in promoting numerous aspects of scientific advancement, and many aspects of basic research programs are intimately related to natural products. The significance, therefore, of the Studies in Natural Product Chemistry series, edited by Professor Atta-ur-Rahman, cannot be overestimated. This volume, in accordance with previous volumes, presents us with cutting-edge contributions of great importance.

  • Science and Engineering of Droplets

    Fundamentals and Applications
    • 1 Edición
    • Huimin Liu
    • Inglés
    This is the first book to encompass the fundamental phenomenon, principles, and processes of discrete droplets of both normal liquids and melts. It provides the reader with the science and engineering of discrete droplets, and provides researchers, scientists and engineers with the latest developments in the field. The book begins with a systematic review of various processes and techniques, along with their applications and associations with materials systems. This is followed by a description of the phenomena and principles in droplet processes. Correlations, calculations, and numerical modeling of the droplet processes provide insight into the effects of process parameters on droplet properties for optimization of atomizer design. Droplets are found in the areas of metallurgy, materials, automotive, aerospace, medicine, food processing, agriculture, and power generation, and encountered in a huge range of engineering applications.

  • Advances in Medicinal Chemistry

    • 1 Edición
    • Volumen 5
    • A.B. Reitz + 1 más
    • Inglés
    Volume 5 of Advances in Medicinal Chemistry contains four intriguing and detailed accounts of the close interface between synthetic chemistry, structure-activity relationships, biochemistry, and pharmacology. In Chapter 1, there is a comprehensive survey of the immunophilin area specifically focussing on neuroregenerative applications in the central nervous system. In Chapter 2, there is an overview of the development of a potent analgesic compound that works via modulation of neuronal nicotinic acetylcholine receptors. In Chapter 3, there is a description of dopamine D-2 autoreceptor partial agonists as potential therapy for the treatment of schizophrenia. In Chapter 4, there is a summary of the successful program in which potent non-peptide inhibitors of HIV protease from the AIDS virus were developed.

  • Advances in Strained and Interesting Organic Molecules

    • 1 Edición
    • Volumen 8
    • B. Halton
    • Inglés
    The eighth volume of this series comprises six chapters and describes a variety of interesting strained and not so strained molecules and their use - or abuse - in the widest sense. This volume contains a position summary of planar carbon networks, the field of strained allenesis addressed by considering the five- to- nine-membered ring derivatives and this is followed by an introduction to the nature of carbene geometry and the use of ESR spectroscopy in deducing carbene structure. The use of strained molecules in the synthesis of important new compounds of a natural and non-natural nature is a main theme in the volume. Other areas that are discussed are strained carbohydrates, stereocontrolled access to natural products and polymer systems as well as a much sought after contribution to the series on small-ring nitrogen heterocycles.

  • Advances in Amino Acid Mimetics and Peptidomimetics

    • 1 Edición
    • Volumen 2
    • A. Abell
    • Inglés
    Peptidomimetics have found wide application as bioavailable, and often potent mimetics of natural peptides. They form the basis of important classes of enzyme inhibitors, they act as receptor agonists and antagonists, and they have even been used to mimic DNA structure. Recent advances in the use of solid-phase organic synthesis have paved the way for the preparation of libraries of these structures to allow the rapid optimization of theri biological properties and hence therapeutic potential. We are also beginning to gain a greater understanding of the structural features of this class of compounds that influence their ability to permeate membranes, and their rate of clearance and metabolism. This volume brings together many of these critical issues by highlighting recent advances in a number of core peptidomimetic-based research.

  • Handbook of Thermal Analysis and Calorimetry

    From Macromolecules to Man
    • 1 Edición
    • Volumen 4
    • Richard B. Kemp
    • Inglés
    The applications and interest in thermal analysis and calorimetry have grown enormously during the last half of the 20th century. These techniques have become indispensable in the study of processes such as catalysis, hazards evaluation etc., and in measuring important physical properties quickly, conveniently and with markedly improved accuracy. Consequently, thermal analysis and calorimetry have grown in stature and more scientists and engineers have become at least part-time, practitioners. People new to the field therefore need a source of information describing the basic principles and current state of the art. The last volume of this 4 volume handbook, devoted to many aspects of biological thermal analysis and calorimetry, completes a comprehensive review of this important area. All chapters have been prepared by recognized experts in their respective fields. The approach taken is "how and what to do and when to do it". The complete work is a valuable addition to the already existing literature.

  • Protein Liquid Chromatography

    • 1 Edición
    • Volumen 61
    • M. Kastner
    • Inglés
    Protein Liquid Chromatography is a handbook-style guide to liquid chromatography as a tool for isolating and purifying proteins, consisting of 25 individual chapters divided into three parts: Part A covers commonly-used, classic modes of chromatography such as ion-exchange, size-exclusion, and reversed-phase; Part B deals with various target protein classes such as membrane proteins, recombinant proteins, and glycoproteins; and Part C looks at various miscellaneous related topics, including coupling reaction, buffer solution additives, and software. The text as a whole can be viewed as a systematic survey of available methods and how best to use them, but also attempts to provide an exhaustive coverage of each facet. How to solve a specific problem using a chosen method is the overall essence of the volume. The principle philosophy of this compilation is that practical application is everything; therefore, both classical and modern methods are presented in detail, with examples involving conventional, medium- and high-pressure techniques. Over-exposure to history, concept, and theory has deliberately been avoided. The reader will find a wealth of tips and tricks from users for users, including advice on the advantages and disadvantages of each method. Easy-to-read sections on "Getting started now" and "Where to go from here" attempt to provide hands-on, fool-proof detailed practical procedures with complete and even standard model runs for any scientist or technician at work in this area.

  • Advances in Inorganic Chemistry

    Cumulative Subject and Author Indexes, and Tables of Contents for Volumes1-47
    • 1 Edición
    • Volumen 48
    • Inglés
    Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bioinorganic to solid state. This acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.

  • Advances in Inorganic Chemistry

    • 1 Edición
    • Volumen 49
    • Inglés
    Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bio-inorganic to solid state. This acclaimed serial features reviews written by experts in the area and is an indispensable reference for advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.

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